Effects of Al addition on the phase transformation and interfacial evolution in multilayer Ti-B4C composite

The fully-dense multilayer Ti-B₄C composite doped with 6 wt% Al was fabricated via tape-casting and hot-pressing sintering at 1800 °C and under a uniaxial pressure of 30 MPa for 60 min. The effects of Al addition on the phase composition, interfacial microstructure and fracture toughness of the laminate composite were investigated. Based on the results of WDS and EDS, Al addition was proved to be effective on accelerating atom diffusion between Ti and B₄C due to the melting pool around interface where liquid Al enriched, besides, it helps to transform the interfacial bonding method of physical to metallurgical. Finally, the improvement on toughness of Al doped composite can be attributed to the strong metallurgical bonding and hybrid fracture mode of interface. Our study may provide a potential method for producing high strength and toughness multilayer metal/ceramic composites.     

废石回收原矿选铜药剂工业优化试验研究

某选矿厂为实现铜资源的高效综合利用,从废石中大量回收原矿,导致原矿性质发生了较大改变,原矿综合铜品位降至0.5%左右。为保证选别质量,确保选厂生产顺利进行,对选厂混合原矿的性质进行了调查,调查结果显示,该选厂混合原矿的铜矿物含量较高,铜综合品位在大于0.5%,且大部分已单体解离。根据该混合原矿的性质,分别进行了选铜捕收剂优化试验,选铜抑锌优化试验,选铜抑砷优化试验,试验结果表明,对该混合原矿进行上述优化试验后,铜精矿中铜的品位可达23.66%,铜回收率可达91.52%,符合选厂要求,实现了铜资源的高效回收。     

深部元素地气迁移的分量化探证据：以郴州金狮岭铀多金属矿床为例

以地气理论为基础的分量化探技术被广泛应用于深部隐伏矿床勘查。深部矿体信息随地气迁移到地表形成叠加异常，分量化探技术可用于采集分析这部分信息来推测深部矿体的赋存状态。以位于湖南省郴州市的金狮岭铀多金属矿床为研究对象，在早期钻探工作、伽马能谱和氡浓度测量成果的基础上，利用分量化探技术探求深部元素地气迁移的证据，为进一步寻找深部隐伏矿床提供理论基础。在该矿区选定了氡浓度异常明显的3条采样线，对采自深度为40~60 cm的浅层土壤147件样品中的U、Pb、Zn等20个元素进行了分量提取和ICP-MS分析，并对分析数据进行了U分量异常特征分析、相关分析、聚类分析，U分量异常地质综合剖面分析以及土壤U分量与伽马能谱U含量的对比分析解译。结果表明：①区内3#、8#测线U分量异常明显，最大值分别为2 194 ng/g和2 167 ng/g，异常衬度值分别为1.298和1.403，区内具有良好的铀矿找矿潜力；②与U分量密切相关的元素为Nd、Sm、Ta，相关系数分别达到0.465，0.492和0.491，远高于99%置信度的临界值0.217，显示其随着地气迁移过程中与U密切相关；③U分量异常主要与深部隐伏矿体、断裂破碎带有关，U分量曲线与Nd、Sm、Ta分量曲线高度吻合，U、Nd、Sm、Ta分量异常组合可作为该区指示深部铀矿体的地球化学标志。     

PPAA: a parallel primitive assembly accelerator in graphics processor

Primitive assembly is an inevitable procedure of graphics rendering which performs the objects preparation for the following steps, however, the conventional approaches suffer from some issues, such as the missing of surface attribute, mismatch of color mode for clipped primitives, and performance bottleneck of rendering pipeline. This paper takes all these issues into considerations, and proposes a parallel primitive assembly accelerator (PPAA) which can solve not only the functional problems but also improve the shading performance. The register transfer level (RTL) circuit is designed and the detailed approach is presented. The prototype systems are implemented on Xilinx field programmable gate array (FPGA) XC6VLX550T and Altera FPGA EP2C70F896C6. The experimental results show that PPAA can accomplish the assembly tasks correctly and with higher performance of 1.5x and 2.5x of two previous implementations. For the most frequently independent primitives, the PPAA can efficiently enhance the throughput by squeezing out the pipeline bubbles and by balancing the pipeline stages.     

磷酸高效分解磷矿实验研究

为改进湿法磷酸生产工艺,提高副产石膏的品质,减少湿法磷酸固体副产物磷石膏堆存产生的经济和环保压力,进行了磷酸分解磷矿制磷酸的实验研究。采用贵州某磷矿为主要原料,研究了湿法磷酸预分解磷矿的反应条件。通过单因素实验确定了湿法磷酸分解磷矿最优反应条件：反应温度为75 ℃,磷酸与磷矿的质量比（液固比）为9,反应时间为3 h,磷酸质量分数为30%（以五氧化二磷计）。在此条件下,磷矿的分解率为98.62%。     

水热法制备Sr_2FeNiO_6催化剂及其催化性能研究

采用水热法制备双钙钛矿催化剂Sr_2FeNiO_6,考察不同浓度KOH溶液(4 mol·L~(-1)、6 mol·L~(-1)、8 mol·L~(-1)、10 mol·L~(-1)、12 mol·L~(-1)、14 mol·L~(-1))对催化剂性能的影响,利用X射线衍射、比表面积测定、程序升温还原和扫描电镜等对样品进行性能表征,并以催化甲烷燃烧为目标,考察催化剂催化性能。结果表明,矿化剂KOH浓度对样品性能影响较大,当浓度为10 mol·L~(-1)时,起燃温度最低,T_(10%)为430℃;浓度为8 mol·L~(-1)时,样品比表面积最大,为19.0 m~2·g~(-1),完全燃烧温度最低,T_(90%)为610℃。     

Research on the sticking-sliding contact ratio in high-speed cutting of cupronickel B10

Journal of Mechanical Science and Technology - Accurate understanding of the frictional behavior at the tool-chip interface is critical for the cutting process. To quantitatively analyze the ratio...     

锂电池回收再生石墨增强水泥性能研究

废弃锂离子电池的负极活性材料主要为石墨,现阶段对于废弃锂离子电池中的石墨主要采用填埋等方法进行处理,造成了资源的浪费和环境的污染。现有的研究表明,废弃锂离子电池中的石墨经高温热解及酸浸处理后可以得到纯净的再生石墨,采用再生石墨增强水泥基复合材料的力学性能和电学性能。结果表明：再生石墨的引入可以增强材料的抗压性能和抗折性能,最大增幅分别达到了57.3%和84.4%。此外,再生石墨的加入有效降低了材料的电阻率,减少了极化时间,当再生石墨的掺加量为3%时,养护28 d后材料的电阻率仅为249 Ω·cm。该复合材料还具有典型的压敏特性。所制备的复合材料有望用于混凝土材料结构的实时动态监测。此外,对于废弃锂离子电池的全组分回收利用及功能水泥材料的研发具有重要意义。     

Morphology,structure, and photovoltaic properties of poly(3‐hexylthiophene) and [6,6]‐phenyl‐C61‐butyric acid methyl ester‐based ternary blends doping with polystyrene of different tacticities

The influence of the polystyrene of different tacticities on the morphology, phase structure, and photovoltaic properties of poly(3‐hexylthiophene) (P3HT) and [6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM) blend has been extensively investigated. The atactic polystyrene (aPS) immiscible with P3HT tended to form the phase‐separated and columnar structure at low aPS weight ratio. Besides, the aPS could migrate to the surface of the films with PCBM phase distributing in the interfaces between P3HT and aPS domains at high aPS weight ratio of 75 wt %. The syndiotactic polystyrene (sPS) immiscible with P3HT could induce the crystallization of P3HT at low weight ratio of 3 wt %. The device based on aPS/P3HT/PCBM ternary blend showed of power conversion efficiency (PCE) of 1.2% even at aPS weight ratio of 50 wt %. However, the device based on sPS/P3HT/PCBM exhibited a sharp decrease in PCE value from 2.3% to 0.6% at sPS weight ratio of 3 wt %, due to the change in film morphology. The performance of the solar cell is believed to be determined by the morphology and phase structure of the ternary blends as revealed by the atomic force microscopy and UV‐vis spectra analysis. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41823.